60.Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes
Simin Wang, Qiao Zhang, Junbo Niu, Xiaobing Guo,Tao Xiong,* and Qian Zhang
Eur. J. Org. Chem. 2022
Utilizing readily available vinylsilanes as the latent nucleophiles to asymmetrically couple with allylic phosphates through CuH catalysis has been successfully developed under very mild reaction conditions. Consequently, a range of optically active organosilanes were synthesized with general good yields with up to 96% ee.