62.Copper-Catalyzed Asymmetric Conjugate Addition of AlkeneDerived Nucleophiles to Alkenyl-Substituted Heteroare
Ying Wang, JianJun Yin, Yanfei Li, Xiuping Yuan, Tao Xiong,* and Qian Zhang
ACS Catal. 2022, 12, 9611−9620
DOI: 10.1021/acscatal.2c01629
61.Remote Site-Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis
Qiao Zhang, Simin Wang, Jianjun Yin, Tao Xiong,* and Qian Zhang
Angew. Chem. Int. Ed. 2022, 61, e202202713
DOI: 10.1002/anie.202202713
60.Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes
Simin Wang, Qiao Zhang, Junbo Niu, Xiaobing Guo,Tao Xiong,* and Qian Zhang
Eur. J. Org. Chem. 2022
DOI: 10.1002/ejoc.202101575
Utilizing readily available vinylsilanes as the latent nucleophiles to asymmetrically couple with allylic phosphates through CuH catalysis has been successfully developed under very mild reaction conditions. Consequently, a range of optically active organosilanes were synthesized with general good yields with up to 96% ee.