60.Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes
Simin Wang, Qiao Zhang, Junbo Niu, Xiaobing Guo,Tao Xiong,* and Qian Zhang
Eur. J. Org. Chem. 2022
DOI: 10.1002/ejoc.202101575
Utilizing readily available vinylsilanes as the latent nucleophiles to asymmetrically couple with allylic phosphates through CuH catalysis has been successfully developed under very mild reaction conditions. Consequently, a range of optically active organosilanes were synthesized with general good yields with up to 96% ee.
59.Cobalt-Catalyzed Radical Hydroamination of Alkenes with NFluorobenzenesulfonimides
Tao Qin, Guowei Lv, Qi Meng, Ge Zhang, Tao Xiong, and Qian Zhang
Angew. Chem. Int. Ed. 2021, 60, 25949– 25957
DOI: doi.org/10.1002/anie.202110178
![17$KSV9UCBENH]YV}[A[18J.png](/static/upload/image/20211216/1639639826169362.png "1639639826169362.png")
58.Copper-catalyzed [3 + 1] cyclization of cyclopropenes/diazo compounds and bromodifluoroacetamides: facile synthesis of alpha,alpha-difluoro-beta-lactam derivatives
Mengru Zhang, Hexin Li, Jinbo Zhao, Yan Li and Qian Zhang
Chem. Sci., 2021, 12, 11805
DOI: 10.1039/d1sc02930d
